Reactive bay functionalized perylene monoimide-polyhedral oligomeric silsesquioxane organic electronic dye
نویسندگان
چکیده
منابع مشابه
Polyhedral Oligomeric Silsesquioxane (POSS)-Based Polymers
A diverse and entirely new class of monomer and polymer technology based on polyhedral oligomeric silsesquioxane (POSS) reagents has been developed. POSS reagents are unique in that they are physically large (approx. 15 Å diameter and 1000 amu) and are composed of a robust silicon–oxygen framework that can be easily functionalized with a variety of organic substituents. Appropriate functionaliz...
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Abstract: The organic/inorganic hybrid materials from polyhedral oligomeric silsesquioxane (POSS, inorganic nanoparticles) and polybenzoxazine (PBZ) have received much interesting recently due to their excellent thermal and mechanical properties, flame retardance, low dielectric constant, well-defined inorganic framework at nanosized scale level, and higher performance relative to those of non-...
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Hybrid materials with superior structural and functional properties can be obtained by incorporating nanofillers into polymer matrices. Polyhedral oligomeric silsesquioxane (POSS) nanoparticles have attracted much attention recently due to their nanometer size, the ease of which these particles can be incorporated into polymeric materials and the unique capability to reinforce polymers. We revi...
متن کاملRh-catalyzed direct arylation of a polyhedral oligomeric silsesquioxane.
The electronic properties of polyhedral oligomeric silsesquioxanes (POSS) have recently been subjected to study. Although theoretical calculations have predicted that POSS can work as an acceptor for π-conjugated organic units, an effective reaction to incorporate aryl groups into a POSS backbone remains to be established. In this work, Rh-catalyzed direct arylation has been developed. Heptaiso...
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In this study, we report UV-MALDI-TOF MS evidence of a fullerene-like silsesquioxane, a high-symmetry polyhedral oligomeric silsesquioxane (POSS or SSO) formulated as R60-Si60O90 or T60 (T = RSiO1.5). The T60 preparation can be performed using a normal hydrolytic condensation of [(3-methacryloxy)propyl]trimethoxysilane (MPMS) as an example. Theoretically, four 3sp3 hybrid orbitals (each contain...
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ژورنال
عنوان ژورنال: Materials Science-Poland
سال: 2015
ISSN: 2083-134X
DOI: 10.1515/msp-2015-0016